Cross-Dehydrogenative Coupling Reactions 铁基催化剂

REVIEW

Fe-CatalyzedCross-DehydrogenativeCoupling

Reactions

LeiyangLv1?ZhipingLi1

Received:1April2016/Accepted:19May2016

óSpringerInternationalPublishingSwitzerland2016

AbstractCross-dehydrogenativecoupling(CDC),whichenablestheformationofcarbon–carbon(C–C)andC–heteroatombondsfromthedirectcouplingoftwoC–HbondsorC–H/X–Hbonds,representsanewstateoftheartinthe?eldoforganicchemistry.Iron,aprominentmetal,hasalreadyshownitsversatileapplicationinchemicalsynthesis.Thisreviewattemptstoprovideacomprehensiveunderstandingoftheevolutionofcross-dehydrogenativecouplingviaironcatalysis,aswellasitsapplicationinsyntheticchemistry.

KeywordsCross-dehydrogenativecoupling(CDC)áIroncatalysisáC–HbondáC–CbondáC–Xbond

1Introduction

Thedevelopmentofselective,ef?cient,sustainable,andenvironmentallybenignsyntheticmethodologiesfortheformationofcarbon–carbon(C–C)andC–heteroatombondsisanareaofgreatinteresttochemists,andonethatisbeingactivelypursued.Carbon–hydrogen(C–H)bondsexistbroadlyinavarietyoforganicmolecules.CatalyticfunctionalizationofC–Hbondshasevolvedasapowerfultoolfororganicsynthesis,whichnotonlyprovidesanatom-economicalternativemethod,butalsoopensnewroutestothetargetmolecules.Thistrendisevidencedbyreportsoftheever-increasingutilizationofC–Hbondsassubstratesforcross-couplingreactions[1–6].Amongreportedmethods,cross-ThisarticleispartoftheTopicalCollection‘‘Ni-andFe-BasedCross-CouplingReactions’’,editedbyArkaitzCorrea.

&ZhipingLizhipingli@ruc.edu.cn

1DepartmentofChemistry,RenminUniversityofChina,Beijing100872,China

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